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Posted 2/9/2007 12:57:39 AM
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We did oil in water analysis using three different methods and we got three different methods.

1. Using HACH mass spectrophotometer: 8.5 mg/l
2. Using gravimetric 8 mg/l
3  Using a combination of GC and GC MS:

C6 - C9 Fraction        28 mg/l
C10 - C14 Fraction     26.8 mg/l
C15 - C28 Fraction     11.8 mg/l
C29 - C36 Fraction     1.85 mg/l

Are those three different methods measured different fraction of hydrocarbon?

This is for regulatory purposes which only mention oil in water should not exceed 30 mg/l. I am confused as to what result I should present to the regulator. Also, which method is normally acceptable?

Thank you for you help.

Post #4024
Posted 2/9/2007 11:33:07 AM
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We did oil in water analysis using three different methods and we got three different methods.

1. Using HACH mass spectrophotometer: 8.5 mg/l
2. Using gravimetric 8 mg/l
3 Using a combination of GC and GC MS:

C6 - C9 Fraction 28 mg/l
C10 - C14 Fraction 26.8 mg/l
C15 - C28 Fraction 11.8 mg/l
C29 - C36 Fraction 1.85 mg/l

Are those three different methods measured different fraction of hydrocarbon?

This is for regulatory purposes which only mention oil in water should not exceed 30 mg/l. I am confused as to what result I should present to the regulator. Also, which method is normally acceptable?

What method (if any) is specified by the regulator?

I would assume the gravimetric method to be the most appropriate. Or, at least, it's the old standby standard method. Are there really methods available using a spectrophotometer?

At the low level found, the error could easily be several mg/l no matter which method is used.

Jeff Naumann
(310) 540-0045
FAX (310) 540-0337
http://www.jeffnaumannassociates.com/
Post #4029
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